Notes, summaries, assignments, exams, and problems for Chemistry

Metal oxides

The Mole Concept

The mole concept is an International System unit of measurement for a substance. It is also represented by carbon-12, and 1 mole is equal to Avogadro's number (6.022 x 10^23).

The Periodic Table's Role in Stoichiometric Calculations

We use the periodic table to get values for given elements in a reaction to obtain their atomic values. We can then use these values for conversion from grams to moles or moles to grams in stoichiometric-based problems (gram/mole, mole-gram conversions).

Heat vs. Enthalpy

Heat is the energy that flows between a system and its surroundings due to a difference in temperature.

Enthalpy is equivalent to the total heat content of a system.

Why Only Enthalpy Explains Energy Associated with Chemical Bonds

Because... Continue reading "Principles of Chemistry: From Stoichiometry to Molecular Orbital Theory" »

Fluorine (F): -1

Chlorine (Cl), Bromine (Br), Iodine (I): 1, 3, 5, 7

Sulfur (S), Selenium (Se), Tellurium (Te): 2, 4, 6

Nitrogen: 3, 5

Phosphorus (P), Arsenic (As), Antimony (Sb), Bismuth (Bi): 3, 5

Carbon (C), Silicon (Si): 2, 4

Boron (B): 3

LIthium (Li), Sodium (Na), Potassium (K), Rubidium (Rb), Cesium (Cs), Francium (Fr), Silver (Ag): 1

Beryllium (Be), Magnesium (Mg), Calcium (Ca), Strontium (Sr), Barium (Ba), Radmium (Ra), Zinc (Zn), Cadmium (Cd): 2

Mercury (Hg), Copper (Cu): 1, 2

Tin (Sn), Lead (Pb), Platinum (Pt), Iridium (Ir), Titanium (Ti): 2, 4

Iron (Fe), Cobalt (Co), Nickel (Ni): 2, 3

Gold (Au): 1, 3

Manganese (Mn): 2, 3, (4, 6, 7)

Aluminium (Al): 3

Chromium (Cr): 2, 3, (6)

Chemistry and Physics Basics

Chemistry

The study of the composition, structure, and properties of matter.

Physics

The study of the principles of matter and energy.

Earth Science

The study of Earth and its neighbors in space.

Matter and Its Properties

Mass

A measure of the amount of matter.

Matter

Anything that has mass and takes up space.

Atom

The smallest unit of an element.

Element

A pure substance that cannot be broken down into simpler substances, made up of atoms.

Compound

Made up of elements and can be broken down into simpler substances.

States of Matter

• Liquid: A state of matter that has a definite volume but not a definite shape.
• Gas: A state of matter with no definite volume or shape.
• Plasma: A high-temperature state of matter in which atoms lose most

Essential Requirements for Dental Impression Materials

• Ability to Record Fine Details: Essential for accurate reproduction.
• Patient Acceptability: Material should be comfortable and well-tolerated.
• Suitable Setting Time: Allows for proper manipulation and setting in the mouth.
• High Tear Strength: Prevents tearing during removal from undercuts.
• Long Shelf Life: Ensures material remains viable for extended periods.
• Easy Manipulation & Inexpensive: Practical for clinical use and cost-effective.
• Accuracy: The ability to precisely record fine anatomical details.
• Stability: The ability to maintain recorded fine details over time.

Factors Affecting Accuracy and Stability

• Sufficient Fluidity: Must be fluid enough to capture intricate details.
• Minimal Dimensional

Ionic Bonds: Electron Transfer

Ionic bonds form when electrons are transferred between atoms, resulting in positively charged cations (+) and negatively charged anions (-).

Covalent Bonds: Electron Sharing

Covalent bonds form when atoms share electrons. This can be visualized by connecting the dots in Lewis structures.

Electronegativity Difference (|ΔEneg|) and Bond Type

• 2.1 - 3.3: Ionic
• 1.7 - 2.0: Borderline (use other information, e.g., boiling/melting points)
• 0.4 - 1.6: Polar Covalent
• 0.0 - 0.3: Non-Polar Covalent

Drawing Covalent Bonds (Lewis Structures)

1. Place the least electronegative element (not Hydrogen) in the center. Count the total number of valence electrons for all atoms.
2. Connect other atoms to the central atom with single bonds (one shared

Tension is a type of stress that a structural element experiences when subjected to two equal and opposite forces pulling outwards along the same axis.

These forces:

• Act on either side of the element.
• Are equal in magnitude.
• Are aligned along the element's axis.
• Pull in opposite directions.

If these forces deform the element, it will stretch. If the element fails, it will break in the middle, perpendicular to the force direction.

Compression is a type of stress that a structural element experiences when subjected to two equal and opposite forces pushing inwards along the same axis.

These forces:

• Act on either side of the element.
• Are equal in magnitude.
• Are aligned along the element's axis.
• Push in opposite directions.

If these forces deform the element,... Continue reading "Structural Element Behavior Under Different Forces" »

- Without H20 being polar, there would be no life on Earth, and Earth will be very dry. Humans and living organisims depend on H20 and it's polarity to sustain life on Earth because h20 wouldnt be able to form hydrogen bonds because it isnt polar. Animals who depend on ice such as polar bears and seals wold not be able to live due to ice not floating on the surface of water. When ice lacks crystal lattice structure, it starts to drown, and this happens due to the lack of hydrogen bonding. Therefore, h20 is very important for life to exist on earth.

- h-h: nonpolar covalent bond

- p-cl: covalent

- na-br: ionic

Electronegativity: 0->0.4 = covalent, 0.5->1.7=polar covalent, more than 1.7= ionic bonds, minus the EN

- Ion-induced dipole force:

DISTILATION PROCESS: ELEMENTS

• Thermometer: measure the temperature of the vapor
• The stopper: hold the thermometer
• The Bunsen Burner: heat the liquid
• The tube at the top of the condenser: conduct the cool water away
• The cool water: cool the vaporized alcohol
• The tube at the bottom of the condenser: conduct cool water in
• The receiving flask: collect the condensed alcohol
• The stand (soporte): maintain an upright or vertical position
• The clamps (pinzas): support the wire
• The wire gauze (rejilla de alambre): spread the flame out
• The ring clamps (pinzas de anilla): grip the flask and the condenser

ORDER

1. Distillation is used...
2. To separate a mixture of liquids...
3. Distillation is a widely used method...
4. The gas is then condensed...
5. Although the term is mostly common.

Electrolysis of Molten Sodium Chloride

Example: Molten sodium chloride:

• Cathode: 2H⁺(aq) + 2e^- → H₂(g) (hydrogen bubbles off)
• Anode: 2Cl^- → Cl₂(g) + 2e^- (chlorine gas produced)

Electrolysis of Aqueous Sodium Chloride

Aqueous solution of sodium chloride:

• At the cathode: Na⁺ and H⁺(aq) are present. H⁺(aq) is discharged because hydrogen is below sodium in the reactivity series. 2H⁺(aq) + 2e^- → H₂(g)
• At the anode: OH^- and Cl^- are present. Cl^- is discharged because it is in high concentration. 2Cl^-(aq) → Cl₂(g) + 2e^-

Positively charged ions move to the negative electrode during electrolysis. They receive electrons and are reduced.

Negatively charged ions move to the positive electrode during electrolysis. They lose electrons and are oxidized.

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