Notes, summaries, assignments, exams, and problems for Chemistry

Chemical Reactions

Types of Chemical Reactions

• Synthesis: A + B → AB
• Decomposition: AB → A + B
• Single Displacement: A + BC → AC + B
• Double Displacement: AB + CD → AD + CB
• Combustion: A + O₂ → H₂O + CO₂ (typically for hydrocarbons)
• Acid-Base: Acid + Base → Salt + Water
• Precipitation: Soluble Salt A + Soluble Salt B → Precipitate + Soluble Salt C

Stoichiometry and Mole Concepts

Key Stoichiometry Relationships

• Mass: 1 mole = Molar Mass (in grams)
• Volume: 1 mole = 22.4 L @ STP (Standard Temperature and Pressure)
• Particles: 1 mole = 6.022 × 10²³ particles (Avogadro's Number)
• Mole-Mole Conversions: Use coefficients from a balanced chemical equation.

Standard Temperature and Pressure (STP)

• Temperature: 0 °C (273.15 K)
• Pressure: 1 atm

Gas Laws

Preparation of Naphthalene

Naphthalene is a fused-ring aromatic hydrocarbon with two benzene rings. It can be prepared via the following methods:

• From Coal Tar: Coal tar, a by-product of coal processing, is a major source of naphthalene. It is extracted and purified using distillation followed by crystallization.
• Synthesis from Benzene: Benzene undergoes a series of reactions to form naphthalene:
  • Alkylation: Benzene reacts with alkyl halides (like methyl chloride) to form methylbenzene (toluene).
  • Cyclization: Toluene undergoes further reaction with chlorine and heat to form naphthalene.

Preparation of Anthracene

Anthracene is a tricyclic aromatic hydrocarbon consisting of three fused benzene rings. It is mainly obtained from coal tar but can also... Continue reading "Synthesis and Sources of Aromatic Hydrocarbons" »

Bonding

Formal Charge: # Valence Electrons - (Nonbonding Electrons + 1/2 Bonding Electrons)

Gases

STP = Standard Temperature and Pressure (273 K or 0°C and 1 atm)

Ideal Gas Law

R = 0.0821 atm x L / (mol x K)

• Pressure (P): Always in atm
  • 760 mmHg = 1 atm
  • 760 Torr = 1 atm
  • 101,326 Pascal = 1 atm
• Temperature (T): Always in Kelvin
• # of Moles (n)
• Volume (V): Always in Liters

Boyle's Law

Occurs when T and n are constant.

Charles's Law

Occurs when P and n are constant.

Avogadro's Law

Occurs when P and T are constant.

Gay-Lussac's Law

Occurs when V and n are constant.

Combined Gas Law

n is constant.

Test

1. a) Valence Electrons for Na⁺ = 0
2. b) Which of the following does not have an octet around the central atom: BCl₃
3. d) A triple bond has a bond order of: 3
4. c) Least electronegative

The environment plays an important role in our lives and people wouldn't be able to live without it. However, we are polluting it every day and it needs to stop. As individuals, we can do lots of things to solve this issue, and this essay will focus on two of them - recycling and the efficient use of energy.

According to recycling, it is the easiest way to see an immediate change and everybody can do it. First, recycling bins are a great method of dividing our waste into paper, plastic, glass, etc., and they can be easily found in every city. Another idea is to reuse the things we have at home and make them new. For example, turning …. 

When it comes to the use of energy, there are many things we can do, especially at home. When we talk about... Continue reading "I choose to live" »

Q#6.3: Define (i) Crystal lattice (ii) Unit Cell.

Ans.(i) Crystal Lattice.

A particular three-dimensional arrangement of particles (atoms, ions, molecules) in a crystal is called a crystal lattice.

In a crystal lattice, particles are located at definite positions in space. These positions are represented by points in a crystal and are called lattice points or lattice sites. This arrangement is called a crystal lattice or space lattice. A crystal lattice actually shows the shape of a crystal.

(ii) Unit Cell.

The smallest geometrical portion of the crystal which is used to build up the whole crystal. OR

If is the smallest portion of a crystal lattice which includes all the positions of each type of particle in the crystal. For example, a cubic crystal... Continue reading "Crystal Lattice and Unit Cell" »

An ion is an atom which has more or less electrons than protons

Hazard Symbols

Hazard symbols explain why a substance must be handled carefully.

Air Pollution from Burning Fossil Fuels

Complete combustion - the fuel reacts completely with oxygen, e.g.:

hydrocarbon + oxygen → carbon dioxide + water

Incomplete combustion - the fuel only partly reacts with oxygen, e.g.:

hydrocarbon + oxygen → carbon dioxide + water + carbon monoxide + carbon (soot)

Impurities in fossil fuels, such as sulfur, also react with oxygen when heated:

sulfur + oxygen → sulfur dioxide

At the very high temperatures in vehicle engines, nitrogen gas from the air reacts with oxygen:

nitrogen + oxygen → nitrogen oxides

Many products from burning fossil fuels are pollutants; they harm habitats and their organisms.

Acid Rain

Acid rain is rainwater... Continue reading "Combustion, Oxidation, and Environmental Impact" »

C

Circumnavigate

To sail or travel all the way around.

Citadel

A fortress defending a city.

Clandestine

Concealed or secret for an evil purpose.

Classic

Of the highest quality.

Cleave

To cling.

Climatic

Having to do with the climate.

Cloister

Covered walk, with columns on one side.

Clone

An exact duplicate.

Clout

A blow.

Cloy

To cause to feel too full when eating; overly sweet.

Coddle

To baby.

Cogitate

To ponder.

Cohort

A group.

Commemorate

To honor the memory of.

Commiserate

To express sorrow or sympathy for.

Commodious

Spacious, roomy.

Compatible

Harmonious.

Competent

Capable.

Compile

To gather together.

Comply

To act or be in accordance with.

Composed

Calm.

Compromise

A settlement of differences in which each side gives up something.

Compunction

Remorse.

Concave

Curved inward.

Concede

To

Chemical Change vs. Phase Change

Chemical change: Produces new substances that didn't exist before.

Phase change: The substance remains the same before and after the process.

Dissolving: It is only a homogeneous mixture; no new substances appear.

Identifying Chemical Changes

How do we know if a chemical change is occurring?

• Gas release: Gases may not be visible; we identify them by bubbles in a liquid.
• Color change
• Thermal energy change
• Energy release as light

Understanding Chemical Reactions

A chemical reaction occurs when the starting substances, called reactants, transform into other new substances, called products.

The appearance of new substances is due to the rearrangement of the reactant's atoms, forming the products. The information about a chemical... Continue reading "Chemical Reactions and Their Impact on Industry" »

Ozone (O3 ) is a made with three oxygen atoms; it is very unstable and has a short lifetime. At room Temperature and pressure has acrid odour and no colour, although at high concentration levels can turn Into blue. At high concentrations can be toxic and can cause death. It s not emitted directly into the air, but is created by chemical reactions between oxides of nitrogen (NOx) and volatile organic compounds (VOC) in the presence of sunlight. VOC + NOx + sunlight tropospheric O3Particulate Matter (PM) "Particulate matter," also known as particle pollution or PM, is a complex mixture of extremely small Particles and liquid droplets. Particle pollution is made up of a number of components, including acids (such as nitrates and sulfates), organic... Continue reading "Divergence in the upper air results, near the surface in: atpl" »