Chemical Energy and Reaction Fundamentals
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Chemical Energy and Molecular Bonds
Chemical energy is the energy associated with chemical bonds and intermolecular attraction. The chemical energy of a set of reacting substances changes since bonds break and form new bonds, creating new products.
We call the energy exchanged in the form of heat between a system containing a chemical reaction and its surroundings the heat of reaction.
Exothermic and Endothermic Reactions
- Exothermic Reaction: The energy of the reactants is greater than that of the products and has a negative sign (e.g., combustion). These reactions release chemical energy via heat.
- Endothermic Reaction: The energy in the system grows. The exchange of energy via heat goes from the surroundings toward the system, so the heat of reaction