Deriving the Van't Hoff Isochore Equation
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Chemist Concept of Free Energy
Derivation of the Van't Hoff Isochore Equation
To discuss the Van't Hoff Isochore Equation, we begin with the equation for the Van't Hoff isotherm:
ΔG° = -RT ln Kp (1)
By differentiating equation (1) with respect to temperature (T) at constant pressure (p):
[∂(ΔG°) / ∂T]p = -R ln Kp - RT [d(ln Kp) / dT]p (2)
Multiply equation (2) by T:
T [∂(ΔG°) / ∂T]p = -RT ln Kp - RT2 [d(ln Kp) / dT]p
Since ΔG° = -RT ln Kp, we can substitute this into the equation:
T [∂(ΔG°) / ∂T]p = ΔG° - RT2 [d ln Kp / dT] (3)
Therefore: ΔG° - T [∂(ΔG°) / ∂T]p = RT2 [d ln Kp / dT]
Integration with the Gibbs-Helmholtz Equation
Now, the Gibbs-Helmholtz equation at standard state is:
ΔG° = ΔH° + T [∂(ΔG°) / ∂T]p
ΔH°... Continue reading "Deriving the Van't Hoff Isochore Equation" »