Notes, summaries, assignments, exams, and problems for Chemistry

Biophysics II

Colloids

Colloids are suspensions of very small particles (micelles), even much larger than the dispersed molecules within a liquid. They are also called pseudo-solutions or colloidal solutions.

State of Sol and Gel

Protoplasmic colloids undergo sol-gel processing, also called reversal or phase change. Colloids present an intermediate state between solid, liquid, and gas. States in the protoplasm of sol and gel usually alternate due to changes in concentration. The most important sols in biology are protein dispersions in water.

Types of Colloids According to the Physical State of the Phases

The dispersant phase can be a solid, liquid, or gas, just as the dispersed phase may be liquid, solid, or gaseous. The passage from a sol to a...

Quantum Numbers

By solving the equations of quantum mechanics for an atom, quantum numbers appear as a mathematical consequence. These describe the behavior of electrons in the atom.

• The principal quantum number, n: Represents an energy level. It can assume any positive integer (1, 2, ...). The first level is the lowest energy, and subsequent levels, increasingly distant from the nucleus, have greater energies.
• The orbital angular momentum quantum number, l: Determines the orbital shape and energy within each level. It takes values between 0 and n-1 inclusive.
• The magnetic quantum number, m_l: Describes the orientation of the orbital in space. Among other things, it explains the splitting of spectral lines when an external magnetic field is applied.

Commercial Gypsum Composition and Purity

The commercial gypsum composition is formed by a mixture of Hemihydrate (HH) and some anhydrous Dihydrate (DH) nuclei, besides the impurities brought from the quarry.

Chemical Composition and Proportions

The typical proportions are:

• Hemihydrate (HH): 20% to 70%
• Anhydrite: 80% to 90%

Sources of Gypsum Impurities

Once obtained, it is necessary to distinguish two types of impurities:

Raw Material Impurities

These come from the source materials. If the gypsum stone contains impurities, these impurities will transfer to the final product.

Manufacturing Process Defects

These are impurities or defects produced during the manufacturing process, such as under-calcined (incocidos) and over-calcined (overcooked) material....

Aluminum

Aluminum is used in telescopes. Tempered powder paint is used in metal protection and the preparation of alloys. Aluminum forms alloys with other metals. Duralumin, an aluminum alloy, is used in aeronautics because it is very lightweight and has great resistance.

Aluminothermy

Aluminothermy is a metal extraction procedure that reduces metal oxides using aluminum powder. Metals such as chromium, manganese, and molybdenum are obtained using this method.

Salts of Aluminum

Important industrial salts are called alum (double salts).

Natural Aluminum

Aluminum is not found free in the Earth's crust. It is named after these characteristics:

1. Alumina
2. Hydroxide
3. Silicates

Obtaining Aluminum

Aluminum is extracted using the electrolytic method. Bauxite and cryolite...

Fundamental Chemistry Concepts

Gas Laws

• Boyle's Law: At constant temperature (T), volume (V) is inversely proportional to pressure (P).
• Gay-Lussac's Law: At constant pressure (P), volume (V) is directly proportional to temperature (T).

Atomic Structure & Periodic Trends

• Quantum Numbers: Describe atomic orbitals: n (principal), l (azimuthal, 0, 1, 2...), m (magnetic, ±l), and s (spin).
• Periodic Table Elements: Transition elements are found in the center of the periodic table. Representative elements are in Groups 1, 2, and 13-18.
• Atomic Radius: ab-IZK

Chemical Bonding & Properties

• Ionic Compounds:
  • No discrete molecules; forces are electrostatic.
  • Upper-middle melting and boiling points.
  • Hard but brittle.
  • Electrical insulators in solid form; conduct

Radioactivity

Radioactivity is the phenomenon whereby some substances emit radiation that can impress photographic plates, ionize gases, produce fluorescence, and cross through opaque to ordinary light. These elements are called radioactive.

Radiation can be:

• Alpha: Positively charged helium atoms, which are easily absorbed by matter.
• Beta: Electrons, which are more penetrating.
• Gamma: Electromagnetic in nature and even more penetrating.

Rutherford Model

The Rutherford model consists of:

• Nucleus: Composed of Z protons and N neutrons, responsible for the atom's mass and positive charge. The mass number A is equal to the sum of protons and neutrons (A = Z + N).
• Electron Cloud: Composed of electrons, responsible for the atom's negative electric charge.

Periodic Table of Elements

7s 7p
6s 6p 6d
5s 5p 5d 5f
4s 4p 4d 4f
3s 3p 3d
2s 2p
1s

Elements are sorted by atomic number and grouped by chemical and physical properties, with 18 groups and 7 periods.

Group

A group consists of elements that have a similar electron configuration at the highest energy level. They have the same number of electrons in the same type of sub-levels, although at different energy levels. The chemical characteristics are similar and depend on the outermost electrons of the atoms. There are 18 groups.

Period

A period comprises all elements whose maximum energy level is the same. There are 7 periods: the 1st has 2 elements, the 2nd and 3rd have 8 elements, the 4th and 5th have 18 elements, and the 6th has 32 elements.

Periodic

Atomic Structure and Chemistry Fundamentals

Organic chemistry is the science of matter. All matter occupies space. Plasma is when atoms are in a high-temperature environment.

• Elements: A single type of atom that cannot be transformed into simpler substances.
• Compounds: Substances formed by different types of atoms combined in a constant ratio.
• Homogeneous: Has a single phase, and components are indistinguishable (H₂O + C₆H₁₂O₆). Can be separated by evaporation or distillation.
• Heterogeneous: Components can be distinguished from each other.
• Phase: A portion of matter with definite limits. Can be separated by filtering or decanting.

d = mass / volume

Prefixes: milli (m) - 10^-3 / micro (μ) - 10^-6 / nano (n) - 10^-9

1 kg = 1000 g and 1 dozen = 12 units

Temperature...

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