Unit Operations in Chemical Engineering

Classified in Chemistry

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Mass Transfer Operations

  • Absorption: The separation of components of a gas mixture using a liquid that dissolves specific components.
  • Distillation: Separating the components of a liquid mixture by vaporization and partial condensation of steam. This can be simple distillation or rectification (with reflux).
  • Extraction: Separation of the components of a mixture through a solvent that is immiscible with it. This may be solid-solid or liquid-liquid extraction.
  • Ion-Exchange: Chemical reactions between ions in a solution and a solid phase that is insoluble in the solution and placed in contact with it.
  • Adsorption: The separation of components of a liquid or gaseous mixture through a solid surface.
  • Electrodialysis: Separation using ion-exchange membranes and applying an electrical potential to concentrate or dilute solutions.
  • Reverse Osmosis: Separation or concentration of electrolytes by increasing pressure on the side of higher concentration.

Heat Transfer Operations

  • Evaporation: The process of concentrating a solute by removing a volatile solvent through evaporation.
  • Gas Conditioning: Modifying the humidity and temperature conditions of an airflow through interaction with a stream of water.
  • Crystallization: The formation of crystalline solid particles within a homogeneous phase.
  • Humidification: The contact between a pure liquid and a gas that is almost insoluble in that liquid.
  • Dehumidification: The process of placing a wet gas in contact with a cooler liquid.
  • Lyophilization: Removing water from a solid by the process of sublimation.
  • Drying: Reducing the water content of a solid, typically through sublimation or evaporation.

Momentum Transfer Operations

  • Fluid Flow: The separation of solid particles in fluid suspension (gas or liquid). This includes internal circulation (fluid inside pipes) and external circulation (solids within the fluid).
  • Flow through Porous Beds: The movement of fluid through a bed of solid particles.
  • Filtration: Separating solid particles suspended in a fluid through a filter medium that only allows the passage of the fluid.
  • Fluidization: The suspension of solid particles from a bed by a fluid passing through it in an upward direction.
  • Sedimentation: Separating suspended solids by gravity, allowing them to settle.
  • Hydraulic Classification: Separating solid particles by size through the entrainment of a liquid.
  • Pneumatic Transport: The dragging and transport of solid particles by a fluid stream.

Mechanical Unit Operations

  • Storage: The containment and preservation of materials.
  • Solid-Polymer Blending: The mixing of solid materials and polymers.
  • Grinding and Crushing: Reducing the size of solids through friction (grinding) or compressive force (crushing).
  • Screening: The separation of particles in a solid mixture based on their size.
  • Centrifugation: The separation of two phases of similar density using centrifugal force.

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