Essential Chemistry Formulas and Molecular Geometry Reference

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Essential Chemistry Formulas and Reference

Miscellaneous Formulas

  • Area of a Circle: 3.14r²
  • Volume: Area × Height
  • Density: Mass / Volume
  • % Composition of Element: [(# of atoms of element) × (atomic weight of element)] / formula weight of substance × 100
  • Molarity: (moles of solute) / (volume of solution in Liters)
  • Bond Order: (# shared electrons) - (# nonbonding electrons) / 2
  • Pressure: Force / Area
  • Pressure × Volume: nRT
  • Density of Gas: (Pressure × Molar Mass) / (R × Temperature)
  • Molarity of Gas: (Density × R × Temperature) / Pressure

Temperature and Chemical Conversions

  • Celsius to Kelvin: K = C + 273.15
  • Kelvin to Celsius: C = K - 273.15
  • Celsius to Fahrenheit: F = 9/5(C) + 32
  • Fahrenheit to Celsius: C = 5/9(F - 32)
  • 1 amu: 1.66054 × 10⁻²⁴ g
  • Grams to Moles: Divide by formula weight
  • Moles to Grams: Multiply by formula weight
  • Moles to Molecules: Multiply by 6.022 × 10²³
  • Molecules to Moles: Divide by 6.022 × 10²³
  • Pressure: 1 atm = 760 torr

Molecular Shapes and Steric Numbers

Steric # = (# of bonds) + (nonbonding electron pairs)

Steric #Electron DomainBonding / NonbondingMolecular Geometry
2Linear2 / 0Linear
3Trigonal Planar3 / 0Trigonal Planar
3Trigonal Planar2 / 1Bent
4Tetrahedral4 / 0Tetrahedral
4Tetrahedral3 / 1Trigonal Pyramid
4Tetrahedral2 / 2Bent
5Trigonal Bipyramidal5 / 0Trigonal Bipyramidal
5Trigonal Bipyramidal4 / 1Seesaw
5Trigonal Bipyramidal3 / 2T-shaped
5Trigonal Bipyramidal2 / 3Linear
6Octahedral6 / 0Octahedral
6Octahedral5 / 1Square Pyramidal
6Octahedral4 / 2Square Planar

Strong Acids and Bases

Strong AcidsStrong Bases
HClLiOH
HBrNaOH
HIKOH
HClO₃RbOH
HClO₄CsOH
HNO₃Sr(OH)₂
H₂SO₄Ba(OH)₂

Energy and Thermodynamics

  • Kinetic Energy (Ek): 1/2mv²
  • Potential Energy (Eel): (kQ₁Q₂)/d
  • Work: Force × distance or -Pressure × ΔVolume
  • Internal Energy: E(final) - E(initial)
  • Enthalpy (H): Internal energy + (pressure × volume)
  • Enthalpy of Reaction: H(products) - H(reactants)
  • Specific Heat: (heat transferred) / (mass × Δtemp)
  • Change in Enthalpy: m × s × ΔT
  • Lattice Energy: K [(Q₁Q₂) / d]

pH Calculations

pH = -log₁₀[H⁺]

[H⁺] = 10⁻ᵖᴴ

Example: pH = -log₁₀(1.4 × 10⁻⁵) = 4.85

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