Essential Chemistry Formulas and Molecular Geometry Reference
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Essential Chemistry Formulas and Reference
Miscellaneous Formulas
- Area of a Circle: 3.14r²
- Volume: Area × Height
- Density: Mass / Volume
- % Composition of Element: [(# of atoms of element) × (atomic weight of element)] / formula weight of substance × 100
- Molarity: (moles of solute) / (volume of solution in Liters)
- Bond Order: (# shared electrons) - (# nonbonding electrons) / 2
- Pressure: Force / Area
- Pressure × Volume: nRT
- Density of Gas: (Pressure × Molar Mass) / (R × Temperature)
- Molarity of Gas: (Density × R × Temperature) / Pressure
Temperature and Chemical Conversions
- Celsius to Kelvin: K = C + 273.15
- Kelvin to Celsius: C = K - 273.15
- Celsius to Fahrenheit: F = 9/5(C) + 32
- Fahrenheit to Celsius: C = 5/9(F - 32)
- 1 amu: 1.66054 × 10⁻²⁴ g
- Grams to Moles: Divide by formula weight
- Moles to Grams: Multiply by formula weight
- Moles to Molecules: Multiply by 6.022 × 10²³
- Molecules to Moles: Divide by 6.022 × 10²³
- Pressure: 1 atm = 760 torr
Molecular Shapes and Steric Numbers
Steric # = (# of bonds) + (nonbonding electron pairs)
| Steric # | Electron Domain | Bonding / Nonbonding | Molecular Geometry |
|---|---|---|---|
| 2 | Linear | 2 / 0 | Linear |
| 3 | Trigonal Planar | 3 / 0 | Trigonal Planar |
| 3 | Trigonal Planar | 2 / 1 | Bent |
| 4 | Tetrahedral | 4 / 0 | Tetrahedral |
| 4 | Tetrahedral | 3 / 1 | Trigonal Pyramid |
| 4 | Tetrahedral | 2 / 2 | Bent |
| 5 | Trigonal Bipyramidal | 5 / 0 | Trigonal Bipyramidal |
| 5 | Trigonal Bipyramidal | 4 / 1 | Seesaw |
| 5 | Trigonal Bipyramidal | 3 / 2 | T-shaped |
| 5 | Trigonal Bipyramidal | 2 / 3 | Linear |
| 6 | Octahedral | 6 / 0 | Octahedral |
| 6 | Octahedral | 5 / 1 | Square Pyramidal |
| 6 | Octahedral | 4 / 2 | Square Planar |
Strong Acids and Bases
| Strong Acids | Strong Bases |
|---|---|
| HCl | LiOH |
| HBr | NaOH |
| HI | KOH |
| HClO₃ | RbOH |
| HClO₄ | CsOH |
| HNO₃ | Sr(OH)₂ |
| H₂SO₄ | Ba(OH)₂ |
Energy and Thermodynamics
- Kinetic Energy (Ek): 1/2mv²
- Potential Energy (Eel): (kQ₁Q₂)/d
- Work: Force × distance or -Pressure × ΔVolume
- Internal Energy: E(final) - E(initial)
- Enthalpy (H): Internal energy + (pressure × volume)
- Enthalpy of Reaction: H(products) - H(reactants)
- Specific Heat: (heat transferred) / (mass × Δtemp)
- Change in Enthalpy: m × s × ΔT
- Lattice Energy: K [(Q₁Q₂) / d]
pH Calculations
pH = -log₁₀[H⁺]
[H⁺] = 10⁻ᵖᴴ
Example: pH = -log₁₀(1.4 × 10⁻⁵) = 4.85