Notes, summaries, assignments, exams, and problems for Chemistry

Binary Compounds

Binary Oxygen Compounds (Oxides)

Systematic Nomenclature

• Prefixes (mono-, di-, tri-, tetra-...) + oxide (element symbol).
• e.g., N₂O₅: Dinitrogen pentoxide.

Stock Nomenclature

• Oxide of (element) + (valence of element in Roman numerals).
• e.g., N₂O₅: Nitrogen(V) oxide.

Binary Hydrogen Compounds (Hydrides)

Metal Hydrides (Hydrogen + Metal)

Systematic Nomenclature

• Prefixes (mono-, di-, tri-, tetra-...) + hydride of (metal).
• e.g., CrH₃: Chromium trihydride.

Stock Nomenclature

• Hydride of (metal) + (valence of metal in Roman numerals).
• e.g., CrH₃: Chromium(III) hydride.

Volatile Hydrides (Hydrogen + Semimetal)

Systematic Nomenclature

• Prefixes (mono-, di-, tri-, tetra-...) + hydride of (semimetal).
• e.g., PH₃: Phosphorus trihydride.

Common Names

• Ammonia

Formulation of Oxides

To formulate oxides, write the element symbol followed by the oxygen symbol, then exchange their valencies and simplify if possible.

• Traditional Naming: Uses specific suffixes based on valency: -ic for one valency; -ous (lower) and -ic (higher) for two; hypo-...-ous, -ous, and -ic for three; and per-...-ic for four.
• Systematic Nomenclature: Uses prefixes such as mono-, di-, tri-, tetra-, penta-, and hexa-.
• Stock Nomenclature: Uses the term "oxide" followed by the metal name and its valency in Roman numerals.

Examples:

• K₂O: Dipotassium monoxide / Potassium oxide
• N₂O₅: Dinitrogen pentoxide / Nitrogen oxide (V)

Hydrides

In hydrides, hydrogen acts with a valency of -1, and valencies are exchanged.

Examples:

• PbH₄: Lead(IV) tetrahydride

Vacuum electronics utilize various types of transducers for pressure measurement. These include bellows mechanical transducers, diaphragm transducers, thermal transducers, and ionization transducers.

Bellows and Diaphragm Transducers

Bellows and diaphragm transducers operate based on the pressure differential between atmospheric pressure and the process being measured. They can be offset relative to atmospheric pressure and calibrated in absolute units. These transducers are suitable for measuring high vacuum. They may be attached to strain gauges or capacitive elements for electrical output.

Thermal Transducers

Thermal transducers are based on the principle of proportionality between the energy dissipated from the hot surface of a filament heated...

Acid-Base Reactions

Acid-base reactions are essential in chemistry, allowing us to determine the concentration of an acid or base solution through titration. This process involves using a solution of known concentration (a standard solution) and an acid-base indicator.

Neutralization

Neutralization is the combination of hydrogen ions (H⁺) and hydroxide ions (OH^-) to form water (H₂O) and a salt. These reactions are exothermic, meaning they release heat.

Acid + Base → Salt + Water

Titration of a Strong Acid with a Strong Base

When titrating a strong acid (e.g., hydrochloric acid, HCl) with a strong base (e.g., sodium hydroxide, NaOH), the reaction is a straightforward neutralization:

HCl + NaOH → NaCl + H₂O

Titration of a Weak Acid with a Weak Base

Titrating...

Material Structure and Properties

Inter-Atomic Bonding

Different materials are made up of different types of bonds. The following are examples and characteristics of the chemical bonds that make up materials.

• Ionic Bonding
  

  Ionic bonding in NaCl. Callister, W. D., & Rethwisch, D. G. (2018). Materials Science and Engineering: An Introduction.

  • Description: Found in compounds composed of metallic and nonmetallic elements; involves atoms at the extremes of the periodic table.
  • Process: Metallic atoms give up their valence electrons to nonmetallic atoms; atoms achieve stable inert gas configurations (filled orbital shells) and acquire electrical charges (become ions).
  • Example: Sodium chloride (NaCl) is a classic ionic material; a sodium atom transfers

Spaghetti Carbonara

Utensils and Ingredients

Utensils

• Large pot
• Large skillet
• Colander
• Large bowl
• Whisk or fork
• Tongs or a pasta fork
• Spoon or ladle

Ingredients:

• 400g spaghetti
• 200g pancetta or bacon, diced
• 4 large eggs
• 1 cup grated Parmesan cheese
• 4 cloves garlic, minced
• Salt and black pepper to taste
• 2 tablespoons olive oil
• Chopped parsley for garnish (optional)

Instructions

1.

Boil the Spaghetti

Start by boiling a large pot of salted water. While waiting, dice the pancetta, mince the garlic, and grate the Parmesan cheese.

2.

Cook the Spaghetti

Once the water boils, add the spaghetti and cook until al dente. Once cooked, reserve about a cup of pasta water before draining.

3.

Sauté the Pancetta and Garlic

In a large skillet, heat the olive oil over medium heat. Add...

Ionic Bonding

Bonding between a non-metal and a metal where electrons are transferred from the metal to the non-metal. This results in the non-metal forming a negative ion and the metal forming a positive ion. The structure is a giant ionic lattice with strong electrostatic forces between ions. A lot of energy is needed to break these forces, resulting in high melting and boiling points. Ionic compounds conduct electricity when aqueous or molten, as the ions are free to move around. They can be represented using dot and cross diagrams.

Covalent Bonding

Bonding between two non-metals. Covalent compounds do not conduct electricity as there are no charged particles. Small molecules are liquids or gases at room temperature due to weak intermolecular...

Halogenation

Halogenation: The reaction of an alkane with a halogen (X2 = F, Cl, Br, I) occurs when a mixture of the two is irradiated with ultraviolet light.

Combustion

Combustion: The reaction of an alkane with O2 occurs during combustion when the alkane is used as a fuel. Carbon dioxide and water are formed as products, and a large amount of heat is released.

An example of a combustion reaction:

CH4 + 2 O2 → CO2 + 2 H2O + Energy

Complete

Complete: C2H6 (g) + O2 (g) → CO2 (g) + H2O (g) + Energy

Incomplete

Incomplete: C3H8 (g) + O2 (g) → H2O (g) + CO2 (g) + CO (g) + C (s) + Energy

Petroleum

Petroleum: Complex mixture of alkanes that can be separated into fractions by distillation. Separating molecules based on differences in boiling points is called...

Electronegativity

Measure of the tendency of an atom to attract bonding pair of electrons.

Cation

Ion that has a positive charge.

Ionic Bond

Chemical bond formed between two ions with opposite charge.

Anion

Ion that has a negative charge.

Chemical Bond

Electrical attraction between nuclei and valence electrons that binds atoms together.

Covalent Bond

Bond formed when atoms share one or more pairs of electrons.

Non Polar Bond

Type of chemical bond where two atoms share a pair of electrons with each other.

Polar

Uneven distribution of charge.

Polar Bond

Type of chemical bond where a pair of electrons is unequally shared between two atoms.

Molecule

Neutral group of atoms that are held together by covalent bonds.

Molecular Compound

Chemical compound whose simplest...

1.Who propossed the theory of One-dimensional consolidation? Karl Terzaghi

2.What types of permeameters exist in Lab tests? Constant head permeameter and Failing head permeameter

3.What is the name of the equation that Governs the 2D underground flow? Laplace’s Equation.

4.Name of the method of draw flow nets That uses iterative calculations. Finite Differences

5.What are the units of the compression Index Cc? Adimensional, NOT UNITS

6.Describe boiling in soils. Boiling of soils occurs when there is an Upward flow and the seepage force is greater that the submerged weight of the Soil.

7.What are the assumptions in laplace’s Equation. Darcy’s law applies, Water and Solids are uncompressible

8.When in it better to use failing head permeameter?