Notes, summaries, assignments, exams, and problems for Chemistry

States of Matter: Solids, Liquids, and Gases

Matter exists in three primary states: solid, liquid, and gas.

The Solid State

The solid state is characterized by fixed mass, volume, and shape because its constituent particles are strongly bonded together. These particles can vibrate slightly but cannot move freely.

• In some solids, particles are regularly arranged, forming shapes with sharp edges, vertices, and planes, which are called lattices.
• When this arrangement is visible to the naked eye, the solid is said to have formed a crystal.
• Glass and plastic possess an amorphous or glassy structure.

The Liquid State

The liquid state is characterized by fixed mass and volume, but variable shape. Liquids take the form of the container that holds them. In... Continue reading "States of Matter: Solids, Liquids, and Gases Explained" »

Periodic Table of Elements

7s 7p
6s 6p 6d
5s 5p 5d 5f
4s 4p 4d 4f
3s 3p 3d
2s 2p
1s

Elements are sorted by atomic number and grouped by chemical and physical properties, with 18 groups and 7 periods.

Group

A group consists of elements that have a similar electron configuration at the highest energy level. They have the same number of electrons in the same type of sub-levels, although at different energy levels. The chemical characteristics are similar and depend on the outermost electrons of the atoms. There are 18 groups.

Period

A period comprises all elements whose maximum energy level is the same. There are 7 periods: the 1st has 2 elements, the 2nd and 3rd have 8 elements, the 4th and 5th have 18 elements, and the 6th has 32 elements.

Periodic

Fundamental Chemistry Concepts

Mixtures: Homogeneous vs. Heterogeneous

Homogeneous means it has a uniform appearance; at first glance, there are no distinct components. A heterogeneous mixture consists of several substances that are visibly separate.

Understanding Solutions

A solution is a homogeneous mixture, consisting of two or more pure substances present in varying amounts. These components can be separated by physical processes.

Solution Components: Solvent and Solute

Normally, the substance found in the largest quantity is called the solvent. The other substances are called solutes.

Solution Concentration: Concentrated/Diluted

A solution is concentrated when it contains a large amount of solute. A solution is dilute when it contains a small... Continue reading "Understanding Fundamental Chemistry Terms" »

Mineralogy and Crystallography

1. Define Polymorphism

Polymorphism refers to the phenomenon where the same chemical substance can exhibit different physical and even chemical properties due to variations in formation conditions, such as pressure and temperature. These variations lead to different arrangements of atoms within the crystal structure.

2. Define Isomorphism

Isomorphism occurs when two or more chemical compounds adopt the same crystalline structure.

3. Define Pseudomorphs

Pseudomorphs are minerals where the internal structure does not correspond to the external crystal form, resulting in a "false form."

4. Define Solid Solution and Mixing

• Solid solution: A homogeneous solid with a variable composition.
• Mixing: A type of solid solution where

Eye Conditions: Myopia and Hyperopia

Myopia

Myopia occurs when the eye has excessive convergence, focusing light from distant objects in front of the retina, resulting in blurred distant vision. This condition is corrected with diverging lenses.

Hyperopia

Hyperopia occurs when the eye is less convergent than normal, causing images of nearby objects to form behind the retina, leading to blurred near vision. This condition is corrected with converging lenses.

Fundamentals of Nuclear Physics

First Model of the Nuclear Atom

The atom consists of a nucleus, which contains almost all of its mass and all of its positive charge. Electrons orbit the nucleus at some distance. The nuclei are formed by two types of particles called nucleons: protons and neutrons.... Continue reading "Understanding Eye Conditions and Nuclear Physics Principles" »

Copper Metallurgy: Pyrometallurgy vs. Hydrometallurgy

The metallurgy of copper depends on the mineral ore. Sulfide ores utilize a pyrometallurgical route to produce anodes or cathodes, while oxide ores use a hydrometallurgical route to directly produce cathodes.

Pyrometallurgy

The cathode production process via pyrometallurgy is as follows: Mineral → Smelting (furnace) → Converters → Refining anode casting → Refining → Cathode.

Copper sulfide ore, with a low grade of 0.5%, requires concentration by flotation. The copper concentrate received in the foundry industry undergoes melting in a furnace, where copper is recovered, and sulfur and iron are removed through oxidation. The copper settles at the bottom and exits the furnace as copper... Continue reading "Copper Extraction: Pyrometallurgy vs. Hydrometallurgy" »

Kinetic Theory of Gases

The kinetic theory explains that gas pressure depends on the volume of the container, the kinetic energy of the gas particles, and their temperature. This theory is fundamental to understanding all states of matter: solid, liquid, and gas.

Gas particles are very small and separated by large distances. They are in constant motion. Gases occupy the entire volume of their container and exert pressure on the container walls. This pressure results from the collisions of gas particles with the walls. The faster the gas particles move, the higher the temperature.

Boyle's Law

When a gas undergoes transformations at a constant temperature, the product of its pressure and volume remains constant (P x V = constant). This can be expressed... Continue reading "Kinetic Theory of Gases: Pressure, Volume, and Temperature Relationships" »

Isotopes and Atomic Structure

Isotopes

Atoms of the same element can have different masses but identical chemical properties. These are called isotopes.

The Neutron

Arranging elements by increasing atomic number resolves anomalies in the periodic table that arise when ordering by atomic mass. Isotopic masses, determined by mass spectrometry, are inconsistent with the mass of protons in the atomic number. Therefore, atomic mass must be explained by other factors.

Atomic Number (Z)

This number indicates the number of protons in the nucleus and defines the element. It is represented by the letter Z.

Mass Number (A)

This number indicates the total number of protons and neutrons (nucleons) in the nucleus and defines the isotope of an element. It is represented... Continue reading "Atomic Structure and Chemical Formulas" »

Elemental Properties & Periodic Trends

Metallic Properties in the Periodic Table

Across a Period

Within the same period, the metallic properties of elements increase as one moves to the left and decrease as one moves towards the right.

Down a Group

Within the same group, the metallic properties of elements increase as one moves down the table and decrease as one moves up.

Essential Elements & Their Occurrence

Bioelements: Building Blocks of Life

Primary Bioelements

These are the most abundant elements in living organisms:

• Hydrogen (H)
• Carbon (C)
• Nitrogen (N)
• Oxygen (O)
• Phosphorus (P)
• Sulfur (S)

Indispensable Secondary Bioelements

These are essential for life, required in smaller amounts:

• Sodium (Na)
• Magnesium (Mg)
• Potassium (K)
• Calcium (Ca)
• Manganese (Mn)

Atomic Model Today

The atomic model today: Matter is discontinuous and composed of small particles in constant motion. This can be observed in two phenomena: diffusion and Brownian motion.

Brownian Motion

Brownian motion is a phenomenon that demonstrates that matter is discontinuous and consists of particles in constant motion.

Atoms

Atoms are the smallest particles that make up matter.

Structure of the Atom

The Nucleus

The atomic nucleus is the core of an atom. It consists of protons and neutrons.

Electrons

Electrons are elementary particles that orbit the nucleus.

Atomic Number and Mass Number

Atomic number is the total number of protons in the nucleus and is designated by the letter "Z".

Mass number is the sum of the protons and neutrons and is designated... Continue reading "Atomic Structure, Chemical Bonds, and States of Matter" »