Notes, summaries, assignments, exams, and problems for Chemistry

Atomic Theory: From Democritus to Quantum Models

Democritus' Atomic Theory

Democritus, in ancient Greece, founded the atomist school. This school, taking a pluralistic approach, proposed that atoms were the fundamental particles. The core principles of atomism are:

1. Atoms move in a vacuum.
2. The shape and size of atoms determine the substance.

Aristotle, conversely, believed that matter was a single, continuous entity.

Dalton's Atomic Theory

John Dalton proposed his atomic theory in the early 19th century. Its key postulates are:

1. Elements are composed of indivisible and indestructible particles called atoms.
2. Atoms of the same element have the same mass and properties.
3. Atoms of different elements have different masses and properties.
4. Chemical compounds are

Understanding Material Systems and the Atmosphere

Background: A material system is a set of interrelated elements considered as a unit for study.

Homogeneous and Heterogeneous Material Systems

Material systems can be homogeneous or heterogeneous.

In a homogeneous system, different substances are not readily apparent.

A mixture is a material system (either homogeneous or heterogeneous) from which different substances can be separated by physical processes.

Solutions and Their Components

A solution is a homogeneous mixture formed by two or more substances in variable amounts, which can be separated by physical means.

In a solution, the substance present in the greater proportion is called the solvent; the others are called solutes.

Separation Techniques

Chemical Bonding and Structure

Forming Molecules

In composites, clustering involves forming molecules. Atoms of different non-metal elements are joined to form molecules.

Ionic Crystals

When metals bind to nonmetals, they form ions of two types. Metals typically form positive ions, and nonmetals form negative ions, which are held together by electrostatic attraction.

For example, a sodium atom gives one electron to a chlorine atom, becoming Na⁺ and Cl^- ions. These ions attract each other. When this happens, many atoms can form a crystal lattice where the ions alternate in a three-dimensional network.

Atomic and Molecular Mass

The atomic mass of an atom is the average mass of its isotopes. It is typically found in the periodic table, often below the... Continue reading "Chemical Bonding, Mass, and Element Types" »

Fundamental Chemistry Concepts

Gas Laws

• Boyle's Law: At constant temperature (T), volume (V) is inversely proportional to pressure (P).
• Gay-Lussac's Law: At constant pressure (P), volume (V) is directly proportional to temperature (T).

Atomic Structure & Periodic Trends

• Quantum Numbers: Describe atomic orbitals: n (principal), l (azimuthal, 0, 1, 2...), m (magnetic, ±l), and s (spin).
• Periodic Table Elements: Transition elements are found in the center of the periodic table. Representative elements are in Groups 1, 2, and 13-18.
• Atomic Radius: ab-IZK

Chemical Bonding & Properties

• Ionic Compounds:
  • No discrete molecules; forces are electrostatic.
  • Upper-middle melting and boiling points.
  • Hard but brittle.
  • Electrical insulators in solid form; conduct

Classification of Matter

Matter is classified as homogeneous or heterogeneous according to its appearance.

• Homogeneous: It looks the same everywhere.
• Heterogeneous: It does not have the same aspect throughout.

Classification of Substances

Substances can be classified according to their material composition into pure substances or mixtures.

• Pure substances: Are formed by a single substance.

Classification of Pure Substances

Pure substances are classified into chemical elements and compounds

• Chemical Elements: Are pure substances that cannot be decomposed into simpler ones.
• Compounds: Are pure substances that can be decomposed into simpler ones.

• Mixtures: A mixture is formed by several pure substances. Mixtures have no fixed composition.

Separation of Mixing

Fundamental Chemical Processes

Reduction: Electron Gain in Chemistry

Reduction is an electrochemical process by which an atom or ion gains electrons, implying a decrease in its oxidation state. This process is the opposite of oxidation.

When an ion or atom undergoes reduction:

• It gains electrons.
• It acts as an oxidizing agent.
• It is reduced by a reducing agent.
• Its oxidation state or number decreases.

Hydration: Water Molecule Addition

The term hydration often refers to hydration reactions. This type of reaction involves the addition of one or more water molecules to a particular compound.

Hydrogenation: Adding Hydrogen to Compounds

Hydrogenation is a type of chemical redox reaction resulting in the addition of hydrogen (H₂) to another compound under... Continue reading "Essential Chemical Processes and Measurement Devices" »

Mole of atom - is the amount of a chemical element equivalent to the atomic mass expressed in grams

Mol substance - ekivalent the quantity k represents the molecular mass expressed in grams (6,022 · 10_23 atomic number)

Molar mass - mass is the substance in 1 mol

Solutions - homogeneous mixture of two or more substances (solute-solvent +)

Molarity - is the way to express the concentration of M = moles solute / volume of solution (l)

Speed of reaction - temperature, concentration, degree of division, nature of reagents, catalysts presence, media pH

theory of collisions - zoquen reactive particles together and break the links that hold together their atoms and are joined forming substances in November

Reagent used for the chemical reaction

... Continue reading "Coh3 chemical name" »

Fundamental Types of Chemical Bonds

The Ionic Bond

The ionic bond results from the electrostatic attractive force between ions of opposite charge, i.e., between a strongly electropositive atom and a highly electronegative atom. This bond usually occurs between a metal and a non-metal.

There is a total electronic transfer from one atom to another, forming ions of opposite charge:

• The metal provides one or more electrons to form positively charged ions, or cations, achieving a stable electronic configuration.
• These electrons then enter the non-metal, forming a negatively charged ion, or anion, which also achieves a stable electron configuration.

The electrostatic attraction between these oppositely charged ions causes them to unite and form an ionic... Continue reading "Chemical Bonds Defined: Ionic, Covalent, and Metallic Structures" »

Physical Properties of Water

The boiling and melting points of water are abnormally high relative to other hydrides in its chemical family. This is primarily due to the existence of hydrogen bonds.

Density Behavior

• From 0°C to 4°C, the density of water increases.
• From 5°C to 100°C, the density decreases.

Heat Capacity and Latent Heats

Water exhibits high values for both heat capacity and latent heats of melting and vaporization.

Definitions:

• Specific Heat Capacity (C_c): The amount of heat required to increase the temperature of a unit mass of a substance.
• Latent Heat (C_l): The heat required to change the state of a substance without increasing its temperature.

Key Values:

• Heat of Vaporization: 539.5 cal/g
• Heat of Fusion: 79.7 cal/g

Climate Regulation