Notes, summaries, assignments, exams, and problems for Chemistry

An Arrhenius acid is a substance that dissociates in water to form hydrogen ions or protons. In other words, it increases the number of H⁺ ions in the water. In contrast, an Arrhenius base dissociates in water to form hydroxide ions, OH^-.

A Bronsted-Lowry acid is a solution that donates protons and is known as a proton donor. The Bronsted-Lowry base, on the other hand, is a solution that accepts protons and is known as a proton acceptor. Going back to a Bronsted-Lowry acid, in general, it must contain a hydrogen ion that it can give up.

Defining Matter

Matter is defined as anything that has mass and takes up space.

Pure Substances

Pure substances possess constant physical properties (e.g., odor, hardness, density, boiling points). They can be classified as either elements or compounds.

Elements

Elements consist of only one kind of atom and cannot be broken down into a simpler type of matter by either physical or chemical means. Elements are found in the periodic table and are categorized as:

• Metals: Tend to lose electrons, resulting in a positive charge (cations).
• Nonmetals: Tend to gain electrons, resulting in a negative charge (anions).
• Metalloids.

Compounds

Compounds are formed when atoms of two or more different elements are chemically bound together. They can be broken down into... Continue reading "Classification of Matter: Elements, Compounds, and Separation Techniques" »

Advanced Materials Science Concepts

High Entropy Alloys (HEAs)

What Materials Are Named ‘High Entropy Alloys’?

Substances constructed with equal or nearly equal quantities of five or more metals. They exhibit a higher degree of fracture resistance, tensile strength, as well as corrosion and oxidation resistance compared to conventional alloys.

What Conditions Must Be Satisfied to Obtain HEA from a Number of Chemical Elements?

Gibb’s phase rule applies: F=C-P+2.

Graphene and Graphene-Like Materials

Differences Between Graphene and Silicene

Silicene is not flat; it is stronger than graphene. Silicene’s hydrogenation reaction is more exothermic than graphene’s.

Three Examples of Graphene-Like Materials

• Layered van der Waals materials
• Graphene-like

Biotic and Abiotic Factors in an Ecosystem

• Chemistry: The study of matter.
• Matter: Any substance that has mass and takes up space.
• Energy: The capacity of a physical system to do work.
• Ecosystem: All of the living things in a given area.
• Biotic: Living organisms (e.g., flowers, plants, bacteria).
• Abiotic: Non-living organisms (e.g., water, soil, air, light, wind).

States of Matter

• Solids: More dense, particles are very close, molecules only vibrate, cannot flow, defined shape, defined volume, not compressible.
• Liquids: Dense, particles are close, molecules have random flow, can flow, adaptable shape, defined volume, very little compressible.
• Gas: Less dense, particles are separated, molecules have a random, fast, and free movement, can flow, no shape,

HOW DO ATOMS BEHAVE DURING A CHEMICAL REACTION?

Chemical reactions occur when bonds between atoms break and new bonds form, creating a new arrangement of atoms and at least one new substance. Observable changes, such as temperature fluctuations, color changes, gas formation, new solids, and odors, accompany these reactions.

Conservation in Chemical Reactions

Besides energy, mass is also conserved during chemical reactions. Lavoisier's experiment disproving the "phlogiston theory" led to the development of the "law of conservation of mass," which states that matter cannot be created or destroyed in a chemical reaction. Balanced chemical equations represent this law.

Energy and Reactions

Energy is required to initiate reactions. Simply mixing chemicals... Continue reading "Understanding Chemical Reactions: From Atoms to Acid Rain" »

Thompson

Thompson was an historian with a Marxist background, whose interests of radical political works set him apart from other authors we studied. He, as Hoggart, followed culturalism, a perspective that stresses human agency, or the active production of culture, and not its passive consumption. His book The Making of the English Working Class embodies this term, since in it he traces the development of the English Working Class between the years 1780 and 1832, more or less the time encompassed by the Industrial Revolution. The book can be seen as a rescue operation of the members (especially radical ones) of the working class lost in the history lead by the deeds of monarchs, statesmen, military leaders and politicians. These other histories... Continue reading "The Making of the English Working Class: A Radical Perspective" »

Types of Solutions

• Solutions are homogeneous mixtures composed of a solute (the substance being dissolved) and a solvent (the dissolving medium).
• Solutions can be categorized based on the state of solute and solvent as solid-solid, solid-liquid, liquid-liquid, and gas-liquid solutions.

Concentration of Solutions

• Concentration measures the amount of solute present in a given amount of solvent or solution.
• Common units of concentration include molarity (M), molality (m), mole fraction (∗X∗), and mass percent (∗w/w∗, ∗w/v∗, or ∗v/v∗).

Colligative Properties

• Colligative properties are properties of solutions that depend only on the number of solute particles and not on their nature.
• These properties include vapor pressure lowering, elevation

Evolution of Atomic Models: Limitations and Contributions

Limitations of Early Atomic Models

Dalton's Atomic Theory: Unexplained Phenomena

• Cathode and Positive Rays Behavior

  1. Cathode ray deflections in the presence of magnetic and electrical fields.
  2. The constancy of the quotient q/m in the particles that constitute cathode rays.

• Existence of Isotopes

  The concept of an element was changed according to Rutherford's model, which Dalton's theory did not account for.

Rutherford's Atomic Model: Theoretical Instability

• Atoms are theoretically unstable systems according to the laws of electromagnetism.
• This model could not explain atomic spectra.

Bohr's Atomic Model: Incomplete Explanations

• It could not explain the spectra of poly-electronic atoms.
• It did not fully

Main Group Elements: Characteristics and Applications

Group 3 Elements (Boron to Thallium)

The elements in Group 3 (Boron, Aluminum, Gallium, Indium, Thallium) share the electron configuration ns²p¹.

Properties of Boron and Aluminum

• Boron (B): A hard, brittle solid with poor electrical conductivity. It primarily forms covalent bonds, such as B-B.
• Aluminum (Al): A shiny, malleable, and ductile metal with good electrical conductivity. Its common oxidation number is +3.

Chemical Reactions and Characteristics

• Boron reacts with Chlorine at high temperatures to form boron trichloride.
• Aluminum burns vigorously when heated in oxygen:

  2Al + 3O2 → 2Al2O3

• Aluminum forms a self-protective layer of aluminum oxide (Al₂O₃) on its surface, which prevents further

Homologous Series

A series of organic compounds having similar structures and similar chemical properties in which the successive members differ in their molecular formula by -CH₂ group.

The different members of the series are called homologous.

Characteristics of Homologous Series

All the member of a homologous series can be described by a common general formula.

Example: All alkane can be described by the general formula C_nH_2n+2.

Each member of a homologous series differ from its higher and lower neighbouring members by a common difference of -CH₂ group.