Notes, summaries, assignments, exams, and problems for Chemistry

Scientific models used to explain why and how atoms form molecules:

• Lewis dot structure
• Valence bond theory

Valence bond theory describes a covalent bond as the overlap of half-filled atomic orbitals (each containing a single electron) that yield a pair of electrons shared between the two bonded atoms. According to valence bond theory, a covalent bond results when two conditions are met: (1) an orbital on one atom overlaps an orbital on a second atom and (2) the single electrons in each orbital combine to form an electron pair.

• Molecular orbital theory

model that describes the behavior of electrons delocalized throughout a molecule in terms of the combination of atomic wave functions. It describes the distribution of electrons in molecules in much... Continue reading "Atomic Models, Periodic Trends, and Chemical Bonding" »

IONIC: thet are solids at room temperatures and have medium to high meltin and boiling points. Ionic bond is strong because it is electrostatic. They are very hard. It is not eassy to scratch an ionic compound. They are fragile. Hitting them forces ions with the same signs together, and they repel and break the crystal. Most disolve well in water, water molecules may surround the ions,weakening their bonds and separating them from the crystal lattice. This is called solvation. They do not conduct electricity well in solid state but hey do in solution or liquid state. SODIUM CHLORIDE

Mixing and Measuring

Agitator

An agitator is a machine used for mixing liquids, typically with an electromagnet.

Beaker

A beaker is a cylindrical container made of glass that is very commonly used in the laboratory, mainly to prepare or heat substances.

Burette

A burette is used for decantation and for transferring and dispensing liquids or fluids.

Graduated Cylinder

A graduated cylinder is used to measure volumes of liquids.

Micropipettes

Micropipettes are used to measure and extract very small amounts of liquids from a solution.

Pipette

A pipette is used to accurately measure volumes of liquids.

Volumetric Flask

A volumetric flask is used to prepare solutions and to know the volume.

Heating and Support

Bunsen Burner

A Bunsen burner is used to heat chemical... Continue reading "Essential Lab Equipment: Uses and Functions" »

Chemistry Fundamentals

Physical Changes

Affect only physical properties like physical state. They do not alter the nature of the substance. Example: Frozen and liquid water have the same composition; nothing changes chemically.

Chemical Changes

Occur when there is a change in the composition of matter. Example: Paper converting into a gas (combustion).

Indicators of Chemical Change

• A gas is produced (bubbles are formed).
• There is a change in temperature due to heat exchange between the environment and reacting substances.
• A precipitate is formed (an insoluble solid that appears as a result of the reaction between solutions).
• The color changes.

Related Concepts

Heat: The interchange of thermal energy between objects or substances having different temperatures.... Continue reading "Fundamental Concepts in Chemistry" »

Distillation: Separating Liquids by Boiling Point

Distillation is a separation process for components of a mixture that have different boiling points. The mixture is heated until it reaches the lower boiling point. One of the substances then becomes vapor and can be separated. This vapor is cooled until it condenses and is collected in a vessel.

Crystallization: Forming Pure Solid Crystals

Crystallization is the process of forming solid crystals from a liquid solution, typically by evaporating the solvent. When all the liquid has evaporated, the solid crystals remain at the bottom of the vessel.

Paper Chromatography: Separating Organic Substances

Paper chromatography is used to separate several organic substances that travel through the chromatography... Continue reading "Chemical Separation Techniques and Mixture Classification" »

Paradigmatic (vertical) axis

The words organizations, groups, and Amnesty International are related to each other because they all belong to the same semantic group, a relationship known as hyponymy. Organizations serve as a hypernym (a more general or superordinate word), while human rights groups and Amnesty International serve as hyponyms (more specific words, in this case types of organizations). The other two kinds of paradigmatic relationships are those of synonymy (prompted = caused) and antonymy (weak/strong).

Syntagmatic (horizontal) axis
 Unlike the paradigmatic relationships, the syntagmatic relationships of a word are not about meaning. They are about the lexical company the word keeps (collocation) and the grammatical patterns

Its function is to complete the measurement circuit, providing a passage from the conductivity-sensing electrode, through the solution, to the reading device. The four parts form an electrical circuit.

Types of Electrodes

1. Hydrogen Electrode
2. Calomel Electrode: Consists of a mixture of mercury and mercurous chloride in contact with a potassium chloride solution.
3. Silver Chloride Electrode
4. Glass Electrode:
   • Parts: Lead-plated, resin-filled rod, internal electrode, sensitive glass.
5. Glass Electrode and Calomel: External calomel reference, two different cells connected in series.

Analysis Methodology

To analyze a substance using potentiometric techniques (anions, cations, organic and inorganic), the substance, or some of its possible complexes, must be electroactive... Continue reading "Potentiometric Analysis: Electrodes, Methods, and Factors" »

Understanding Chemical Bonds

Ionic Bond: This bond occurs when metallic elements interact with non-metal atoms. In this case, the metal atoms donate electrons to the non-metal atoms, becoming positively and negatively charged ions, respectively. These oppositely charged ions are attracted by strong electrical forces, being tightly bound and giving rise to an ionic compound. These electrical forces are called ionic bonds.

Covalent Bond: Covalent bonds are the forces that hold non-metallic atoms together. These atoms have many electrons in their outermost level (valence electrons) and tend to gain electrons rather than transfer them to acquire the stability of the electronic structure of a noble gas. Therefore, electrons from non-metallic atoms... Continue reading "Understanding Chemical Bonds: Ionic, Covalent, and Metallic" »

Understanding Atomic Structure and Models

What is a Subatomic Particle?

A subatomic particle is a particle smaller than an atom. It can be an elementary particle or a composite particle, in turn, composed of other subatomic particles such as quarks, which make up protons and neutrons.

Dalton's Atomic Theory: Foundations of Chemistry

Key Postulates of Dalton's Theory

1. Elements are composed of tiny particles called atoms.
2. All atoms of a given element are identical in mass and properties.
3. Atoms of one element differ from those of any other element; atoms of different elements can be distinguished by their relative atomic weights.
4. Atoms of one element combine with atoms of other elements to form chemical compounds. A given compound always has the same relative