Chemical Hazard Analysis: Prevention and Mitigation Strategies

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Chemical Hazard Analysis: Prevention and Mitigation

Bromine Exposure

Hazard: Bromine

Consequence: Bromine Exposure

Preventative Safeguards:

  • Routine System Pressure tests
  • SHE critical Procedures
  • Kynar Lined piping/glass vessels
  • Hose inspection/integrity
  • Equipment Strategy
  • Safety Critical Instrumentation
  • Materials of construction

Mitigating Safeguards:

  • Bromine Detectors
  • Automated Trip systems
  • Containment Sump
  • Emergency Response
  • PVC containment pipe

Situations Leading to Scenario:

  • Hose failure during Bromine Unloading
  • Leak from Bromine Facilities/piping
  • Long term corrosion of pipe supports
  • Liquid overfill

Isoprene Storage

Hazard: Isoprene Storage

Consequence: BLEVE (Boiling Liquid Expanding Vapor Explosion)

Preventative Safeguards:

  • Safety Critical drain procedure
  • Over pressure/Vac protection
  • PSV N2 Sweep
  • Redundant level instruments
  • Inspection program

Mitigating Safeguards:

  • Deluge/firewater coverage
  • Water flood facilities
  • Emergency response
  • Spill containment area
  • HC detectors
  • Structural fireproofing

Situations Leading to Scenario:

  • Over pressure due to popcorn polymer coating PSV
  • Leak during water draw activities
  • Liquid overfill
  • Pump seal leaks

Refrigerant & Recycle Storage

Hazard: Refrigerant & Recycle storage

Consequence: BLEVE (Boiling Liquid Expanding Vapor Explosion)

Preventative safeguards:

  • Over pressure protection
  • Equipment strategy/inspection
  • AVO checks
  • High level alarms

Mitigating safeguards:

  • Deluge/firewater coverage
  • Emergency response
  • HC detectors
  • Structural Fireproofing
  • Remote isolation

Situations Leading to Scenario:

  • Opening equipment in light hydrocarbon service
  • Corrosion under insulation
  • Liquid overfill
  • Pump seal leaks

High Pressure Ethylene Service

Hazard: High pressure ethylene service

Consequence: Vapor Cloud Explosion

Preventative safeguards:

  • SHE critical temp alarms
  • Procedures
  • Over pressure protection
  • Compressor surge control

Mitigating safeguards:

  • HC detectors
  • Emergency response
  • Deluge/firewater coverage

Situations Leading to Scenario:

  • Operating C-100 under zero load
  • Operating C-100 without C-200

Cold Service HC Equipment

Hazard: Cold service HC equipment

Consequence: BLEVE/Vapor Cloud Explosion

Preventative safeguards:

  • MSOT alarms
  • Pressure control

Mitigating safeguards:

  • Deluge/firewater coverage
  • Emergency response
  • HC detectors

Situations Leading to Scenario:

  • Clearing/commissioning equipment with N2
  • Compressor trip pressuring up vacuum equipment
  • Cold day start up of high MDMT equipment
  • Back pressure control failure

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