Chemical Hazard Analysis: Prevention and Mitigation Strategies
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Chemical Hazard Analysis: Prevention and Mitigation
Bromine Exposure
Hazard: Bromine
Consequence: Bromine Exposure
Preventative Safeguards:
- Routine System Pressure tests
- SHE critical Procedures
- Kynar Lined piping/glass vessels
- Hose inspection/integrity
- Equipment Strategy
- Safety Critical Instrumentation
- Materials of construction
Mitigating Safeguards:
- Bromine Detectors
- Automated Trip systems
- Containment Sump
- Emergency Response
- PVC containment pipe
Situations Leading to Scenario:
- Hose failure during Bromine Unloading
- Leak from Bromine Facilities/piping
- Long term corrosion of pipe supports
- Liquid overfill
Isoprene Storage
Hazard: Isoprene Storage
Consequence: BLEVE (Boiling Liquid Expanding Vapor Explosion)
Preventative Safeguards:
- Safety Critical drain procedure
- Over pressure/Vac protection
- PSV N2 Sweep
- Redundant level instruments
- Inspection program
Mitigating Safeguards:
- Deluge/firewater coverage
- Water flood facilities
- Emergency response
- Spill containment area
- HC detectors
- Structural fireproofing
Situations Leading to Scenario:
- Over pressure due to popcorn polymer coating PSV
- Leak during water draw activities
- Liquid overfill
- Pump seal leaks
Refrigerant & Recycle Storage
Hazard: Refrigerant & Recycle storage
Consequence: BLEVE (Boiling Liquid Expanding Vapor Explosion)
Preventative safeguards:
- Over pressure protection
- Equipment strategy/inspection
- AVO checks
- High level alarms
Mitigating safeguards:
- Deluge/firewater coverage
- Emergency response
- HC detectors
- Structural Fireproofing
- Remote isolation
Situations Leading to Scenario:
- Opening equipment in light hydrocarbon service
- Corrosion under insulation
- Liquid overfill
- Pump seal leaks
High Pressure Ethylene Service
Hazard: High pressure ethylene service
Consequence: Vapor Cloud Explosion
Preventative safeguards:
- SHE critical temp alarms
- Procedures
- Over pressure protection
- Compressor surge control
Mitigating safeguards:
- HC detectors
- Emergency response
- Deluge/firewater coverage
Situations Leading to Scenario:
- Operating C-100 under zero load
- Operating C-100 without C-200
Cold Service HC Equipment
Hazard: Cold service HC equipment
Consequence: BLEVE/Vapor Cloud Explosion
Preventative safeguards:
- MSOT alarms
- Pressure control
Mitigating safeguards:
- Deluge/firewater coverage
- Emergency response
- HC detectors
Situations Leading to Scenario:
- Clearing/commissioning equipment with N2
- Compressor trip pressuring up vacuum equipment
- Cold day start up of high MDMT equipment
- Back pressure control failure