Notes, summaries, assignments, exams, and problems for Chemistry

Photosynthesis: Anabolic Process Converting Inorganic to Organic

Photosynthesis converts inorganic matter into organic using solar light. Sunlight's energy is converted into chemical energy within organic compounds. During photosynthesis, oxygen (O2) is released into the atmosphere. The overall process can be summarized as: CO2 + H2O + Light -> Organic Matter + O2.

However, this simplified equation doesn't reflect the actual process. The oxygen released comes from water, not carbon dioxide. Glucose formation and oxygen release are independent processes.

Light Phase (Hill Reaction)

The light phase occurs in the thylakoids, where photosystems are located. It requires light and produces:

• Reducing power: NADPH + H+
• Energy: ATP (produced using sunlight)

Understanding Material Systems and Separation Techniques

Heterogeneous system material should appear uniform. Akella system material is presented uniformly. All points of the material system are separated for experimental study.

Decompose a compound using chemical procedures into simple substances. A simple substance is a pure substance that cannot be decomposed into other simpler substances by ordinary chemical procedures. A simple substance is formed by a single type of element. A compound is a pure substance formed by two elements combined in fixed, homogeneous proportions.

Dissolving creates a blend made uniform by two pure substances in variable proportions.

Simple Distillation

Used to separate a dissolving liquid formed by two points with... Continue reading "Understanding Heterogeneous and Homogeneous Systems" »

Metals: Properties, Processing, and Applications

Copper

Classification: Density > 5. Danger 5-2, Ultralight < 2.

Advantages: Electrical and thermal conductivity, oxidation and corrosion resistance, low melting point.

Disadvantages: Lower mechanical resistance, more difficult and expensive to obtain.

Sources:

• Native copper: (Poor mineral, not usually found)
• Sulfides: Chalcopyrite and chalcocite
• Oxides: Malachite and cuprite

Characteristics: Reddish, relatively soft, high electrical conductivity, very ductile and malleable, moderate resistance to acids.

Obtaining Process:

• Wet process: Copper < 10%. Diluted sulfuric acid is added to an electrolytic bath.
• Dry process: Copper > 10%. Crushing, grinding, mineral separation, and gangue by flotation

Ketogenesis

Ketogenesis is the biochemical process by which ketone bodies are produced as a result of fatty acid breakdown.

Phase 1: Acetoacetyl-CoA Formation

Acetyl-CoA + Acetyl-CoA → Acetoacetyl-CoA

Phase 2: HMG-CoA Synthesis

Acetoacetyl-CoA + Acetyl-CoA + H₂O → Hydroxymethylglutaryl-CoA (HMG-CoA)

Phase 3: Ketone Body Production

Hydroxymethylglutaryl-CoA (HMG-CoA) → Acetoacetate → Acetone AND β-Hydroxybutyrate

Deamination of Amino Acids

Deamination is the removal of an amino group from an amino acid.

Non-Oxidative Deamination

Serine Complex Unstable → Imino Acid → Pyruvic Acid + Ammonia (NH₃)

Oxidative Deamination

Amino Acid (AA) → Imino Acid → Keto Acid + Ammonia (NH₃)

Glycolysis

Glycolysis is the metabolic pathway that converts... Continue reading "Key Metabolic Pathways and Biochemical Processes" »

Fundamentos da Termodinâmica

O Que é Calor?

Calor é a grandeza física que mede a energia térmica que passa de um corpo para outro devido à diferença de temperatura entre eles.

Definição de Caloria

Caloria: É a quantidade de calor necessária para elevar a temperatura de 1g de água de 14.5 ºC para 15.5 ºC.

Calor Sensível e Calor Latente

Calor Sensível: Ocorre quando há apenas mudança de temperatura. Ex: aquecimento de um metal.

Calor Latente: Ocorre quando há mudança de estado físico e não de temperatura. Ex: derretimento do gelo.

Calor Específico das Substâncias

Calor Específico: Diferentes substâncias necessitam de quantidades distintas de calor para um aumento de 1 ºC. Ex: Ferro (Fe) = 0.11 cal/g°C. Isso significa que para... Continue reading "Fundamentos da Termodinâmica: Conceitos Essenciais de Calor e Energia" »

XRD for Stress Measurement in Surface Engineering

X-Ray Diffraction (XRD) techniques are employed for stress measurements, particularly in surface engineering. It utilizes Bragg's Law (stated in the source as 2d sin σ, where d is the lattice spacing and σ is related to the diffraction angle; the general form is often 2d sin θ = nλ) and the material's elastic properties to correlate lattice strain with stress values.

Principles and Application

XRD analyzes the diffraction pattern of X-rays interacting with a crystalline material to determine its atomic and molecular structure, including lattice strains which are related to stress.

Advantages of XRD

• Non-destructive
• Fast and simple to perform
• Can be performed in situ (on-site)
• High accuracy for many

Le Chatelier's Principle

Changes in Concentration

When a quantity of a substance is added to an equilibrium system, it will move to the side where the substance is not present. If, however, we remove one of the substances, the equilibrium shifts to the side where it is located.

Changes in Pressure Affecting Volume

When the pressure is increased from the outside and the system decreases in volume, the equilibrium shifts in the direction where there is a smaller number of moles (or molecules) to counteract the external perturbation.

Changes in Temperature

An increase in temperature always favors the endothermic process, and a decrease favors the exothermic process. If the direct process is endothermic, a temperature increase leads to a higher value... Continue reading "Le Chatelier's Principle and Carbon Chemistry Properties" »

Understanding Vapor Pressure and Colligative Properties

Colligative Properties and Vapor Pressure

Liquids are composed of molecules in constant motion. Upon reaching the surface, these molecules can acquire enough energy to transition from the liquid to the gaseous state (i.e., become vapor). If they retain sufficient energy, they remain in the gaseous state; otherwise, they return to the liquid state.

Defining Vapor Pressure

When equilibrium is established between a liquid and its vapor in an enclosed space, the pressure exerted by the vapor over the liquid has a specific value at a given temperature. This is known as vapor pressure.

Factors Affecting Vapor Pressure

• Temperature

  An increase in temperature enhances the kinetic energy of molecules,

Properties of Matter

Properties of matter help us describe and identify substances.

General Properties

These are properties common to all matter, such as mass and volume. They do not help distinguish one substance from another.

Characteristic or Intensive Properties

These properties are unique to a specific substance and do not depend on the amount of matter present. They are useful for identifying a substance. Examples include density and melting point.

Extensive Properties

These properties depend on the amount of matter present. Examples include mass and volume.

Fundamental Chemical Concepts

Relative Atomic Mass

The relative atomic mass of a chemical element is the ratio of the average mass of atoms of an element to one twelfth of the mass of an atom... Continue reading "Foundations of Chemical Principles" »

Proton: Positive electricity - 1.602 x 10^-19 electric charge and its mass is greater than 27 kg. 1.672 x 10^-27 kg. Electron: Electric negative charge (mass is approximately 0.000548 Daltons). Neutron: Neutral charge (mass is almost equal to that of the proton, 1.675 x 10^-27 kg).

Concept of Mole: A practical means to handle the large number of particles involved in a chemical reaction. If two quantities have the same number of atoms or molecules, their masses are in the same proportion as their respective atomic or molecular masses. The mole is the unit of the number of particles contained in an amount of substance equal to its molar mass. This number is called Avogadro's number (the number of atoms in 12 grams of Carbon-12). Atomic mass is expressed... Continue reading "Understanding Protons, Electrons, and Chemical Bonds" »