Notes, abstracts, papers, exams and problems of Chemistry

Understanding Chemical Oxides

Binary combinations between oxygen and all other chemical elements except the noble gases and fluorine.

Formulating Oxides

Oxides have the following general formula: X₂O_n, where:

• X is the symbol of the other element.
• 2 corresponds to the valence of oxygen.
• O is the symbol for oxygen.
• n is the valence of the other element (metal or nonmetal).

Naming Oxides: Three Classifications

Oxides are named using three classifications: Traditional, Systematic, and Stock.

Traditional Nomenclature for Oxides

Basic Oxides: These result from the combination of oxygen and a metal.

• If the metal has a single valence, the oxide is named "Oxide" followed by the name of the metal.

Examples:

• CaO: Calcium Oxide
• Na₂O: Sodium Oxide

• If the metal has two

Laws of Melting

When a pure substance melts, it exhibits specific behaviors:

1. It melts at a specific temperature, called the melting point.
2. While melting, the temperature remains constant, even with the coexistence of solid and liquid phases.
3. All pure liquids, when sufficiently cooled, solidify at the same temperature at which they melt.
4. During solidification, the temperature remains constant.

Melting Point and Solidification

The melting and solidification points of a pure substance are characteristic properties that can be used to identify it.

A substance whose temperature varies during a state change cannot be considered a pure substance.

Vaporization

Vaporization is the change of state from liquid to vapor (or gas). It can occur in two ways: boiling... Continue reading "Understanding Changes of State: Melting, Boiling, and Sublimation" »

Noncyclic Photophosphorylation

This process is similar to what occurs after the electron transport chain in the mitochondrial membrane.

• With the stroma, protons are transported to the lumen through the fixed plastoquinone.
• This generates a potential gradient that moves to an enzyme, ATPase, located in F particles, similar to those of mitochondria.
• ATPase uses four protons to phosphorylate ADP to ATP.

Cyclic Photophosphorylation

This occurs when:

• Light striking the plant is between 681 and 700 nm, exciting only Photosystem I (PSI).
• The plant urgently needs ATP, as this process is faster than noncyclic photophosphorylation and does not waste energy reducing NADP when not needed.

The process unfolds as follows:

1. PSI donates electrons to the acceptor chain,

Electron Transport Chain

Steps in the Electron Transport Chain

1. Electrons and protons carried by NADH + H⁺ are transferred to FMN, reducing it.
2. FMN is oxidized, transferring its electrons to Coenzyme Q (CoQ), which is reduced. This allows FMN to accept more electrons and continue the chain.
3. CoQ is oxidized and passes its electrons to the next acceptor, a cytochrome. Cytochromes are dehydrogenases.
4. Cytochromes transport protons into the mitochondrial matrix. The chain continues with the electrons.
5. Cytochromes are iron-sulfur molecules. The iron is oxidized (ferric) or reduced (ferrous) Fe. Each iron atom carries one electron, so the process occurs twice.
6. Cytochromes following CoQ in the chain are Cyt b, Cyt c, and Cyt a3.
7. Electrons reach the end of

Characteristics of Matter

Matter has mass; that is, when placed on a scale, it creates an imbalance. Matter is impenetrable, as two bodies cannot occupy the same space simultaneously. Matter occupies a space, meaning it has volume. The common component is called matter. Bodies are a limited portion of matter, distinguished by features such as color, texture, smell, etc. Each particular kind of matter is a substance, such as sulfur, cotton, or sugar.

Intensive Properties

Intensive properties do not depend on the amount or form of the substance. Examples include:

• Chemical composition
• Vapor pressure
• Density
• Effusion point
• Fragrance
• Taste

Extensive Properties

Extensive properties directly depend on the amount of substance. Examples include:

• Mass
• Volume
• Smell
• Surface
• Height
• Weight

States

Cytology Fixatives

Solution: Cytology fixatives, formerly employing ether/alcohol 96 in equal parts, are now rarely used due to the hazardous nature of ether. The 96% alcohol is most often used. The procedure involves immersing the preparation in the fixative bath for a minimum of 10 to 15 minutes. Other alcohols, such as 100% methanol, 80% propanol, and 80% isopropanol, can also be used. Citospray is used in samples obtained by forced exfoliation.

Sample Types in a Cytology Laboratory

Samples that can reach the lab from samples obtained by:

• Forced exfoliation: Rubbing or scraping with various instruments. This is applied to the skin and organs accessible from the outside.
• Spontaneous exfoliation: Samples containing spontaneously exfoliating

ZOE Impression Paste

Advantages: Good adhesion, adequate working time, requires no insulation to the plaster model, is fluid allowing copying of fine details, and is economical.

Disadvantages: The Eugenol is acidified, and some patients are allergic to eugenol.

Elastomers

Organic materials formed by weak interaction with polymer molecules, forming a three-dimensional network with elastic properties.

Mercaptan Elastomers

Elastic impression materials with mercaptan groups in the polymer chain, which when hardened, forms a semisolid paste.

Synonyms: Polysulphide rubber, synthetic rubber, tiocoles.

Commercial presentation: Pasta-pasta

Consistencies: Light, regular, heavy.

Chemical Composition:

Paste: Polysulfide polymer (base), titanium dioxide (filler) can... Continue reading "Dental Impression Materials: ZOE Paste & Elastomers" »

Substances, Mixtures, and Separation Techniques

1. Pure Substances vs. Mixtures

• Distilled Water: Pure substance/compound
• Tap Water: Mixture/homogeneous
• Diamond: Pure substance/element
• Gasoline: Mixture/homogeneous
• Wine: Mixture/homogeneous
• Air: Mixture/homogeneous

2. Dalton's Theory

• Matter is made up of indivisible and indestructible atoms.
• All atoms of the same element are equal in mass and properties.
• Compounds are formed by the combination of different elements.

3. Separation Techniques

• Screening: Separates solid particles of different sizes. Instrument: sieve.
• Filtration: Separates solids from liquids. Instrument: filter.
• Evaporation: Separates solids from liquids when the liquid is not needed. Works best with homogeneous mixtures. The process is faster

Aluminum

Aluminum is used in telescopes. Tempered powder paint is used in metal protection and the preparation of alloys. Aluminum forms alloys with other metals. Duralumin, an aluminum alloy, is used in aeronautics because it is very lightweight and has great resistance.

Aluminothermy

Aluminothermy is a metal extraction procedure that reduces metal oxides using aluminum powder. Metals such as chromium, manganese, and molybdenum are obtained using this method.

Salts of Aluminum

Important industrial salts are called alum (double salts).

Natural Aluminum

Aluminum is not found free in the Earth's crust. It is named after these characteristics:

1. Alumina
2. Hydroxide
3. Silicates

Obtaining Aluminum

Aluminum is extracted using the electrolytic method. Bauxite and cryolite... Continue reading "Aluminum, Copper, Polymers, and Ceramics: Properties and Uses" »

Fuel Properties and Combustion

Oil is formed by the decomposition of organic matter, primarily plankton, in marine environments. It contains the remains of animals and is a mineral found in sedimentary rock formations.

Soluble compounds begin to form, undergoing thermal decomposition into hydrocarbons (HC).

Gaseous Fuels

Gaseous fuels, also called hydrocarbons (HC), are designed for use in combustion. They are divided into natural gas fuels and manufactured gaseous fuels.

Advantages and Properties of Gaseous Fuels

The calorific value varies greatly depending on the type of gas and the presence of non-combustible components. Non-combustible components lower the heat efficiency of combustion.

Calorific value is the heat released during combustion.

Specific