Notes, summaries, assignments, exams, and problems for Chemistry

Halogenation

Halogenation: The reaction of an alkane with a halogen (X2 = F, Cl, Br, I) occurs when a mixture of the two is irradiated with ultraviolet light.

Combustion

Combustion: The reaction of an alkane with O2 occurs during combustion when the alkane is used as a fuel. Carbon dioxide and water are formed as products, and a large amount of heat is released.

An example of a combustion reaction:

CH4 + 2 O2 → CO2 + 2 H2O + Energy

Complete

Complete: C2H6 (g) + O2 (g) → CO2 (g) + H2O (g) + Energy

Incomplete

Incomplete: C3H8 (g) + O2 (g) → H2O (g) + CO2 (g) + CO (g) + C (s) + Energy

Petroleum

Petroleum: Complex mixture of alkanes that can be separated into fractions by distillation. Separating molecules based on differences in boiling points is called... Continue reading "Halogenation, Combustion, Complete and Incomplete Reactions, Petroleum, Refining, Alkenes" »

UNIDAD 3 PARTE 2

electron affinity. How much an atom wants to gain an electron. UP AND RIGHT. Electron affinity gets higher, which causes the atom to want to GAIN electrons. Fluorine has the highest, and francium has the lowest. 

No electron affinity: Noble gases. They have a full outer shell and do not need more electrons

ionization energy. The energy required to REMOVE  an electron from the valence shell of an atom . If it is easy to remove an electron, the energy will be low (like if an atom wants to lose its electrons). If it is hard to remove an electron, the energy will be high (like if an atom doesn't want to lose its electrons). UP AND RIGHT. Gets higher because your gaining electrons. Helium has the highest and francium has the lowest.... Continue reading "+coh3 ion" »

Unit 3, Part 1: Core Chemistry Principles

Transition Metals: Unique Properties Explained

It is surprising that transition metals exhibit similar physical and chemical properties despite having varying numbers of valence electrons.

Unlocking Information from the Periodic Table

The periodic table is a powerful tool from which you can determine:

• Number of protons
• Number of neutrons
• Number of electrons
• Atomic mass
• Atomic number
• Element name
• Atomic symbol
• Valence electron shells
• Total electron shells

Defining Atomic Identity: The Proton

The proton defines the identity of an atom. Its number corresponds to the atomic number, which uniquely identifies each element. The number of protons in an atom never changes.

Subatomic Particle Locations

Each subatomic particle... Continue reading "Atomic Structure & Properties: Essential Chemistry Concepts" »

Unit 1: Matter and Mixtures

Mixtures are combinations of two or more substances that are not chemically combined. They keep their physical properties and can be separated by physical means.

Homogeneous and Heterogeneous Mixtures

• Homogeneous Mixtures: These are uniform throughout. Components cannot be seen, and they cannot be filtered.
  • Solutions: Evenly distributed liquids that do not filter; substances are dissolved (e.g., salt and water).
  • Alloys: Two or more elements where at least one is a metal; these can be separated but not by simple physical means.
  • Colloids: These can be separated (e.g., mayonnaise or gelatin).
• Heterogeneous Mixtures: These are non-uniform. Components can be seen.
  • Suspensions: These can be filtered as large particles are visible

Galvanic Reaction in the Mouth

Biting on aluminum foil can be painful and is usually noticed if you have metal in your mouth from dental work (e.g., fillings, crowns). Basically, when you bite on foil, you set up a battery in your mouth, and the electrical current stimulates nerve endings in your tooth. Here is what happens:

• Pressure from biting brings two dissimilar metals (aluminum foil, mercury in fillings, or gold in crowns) in contact in a moist, salty environment (saliva).
• The two metals have an **electrochemical potential difference** or voltage across them.
• Electrons flow from the foil into the tooth (i.e., **electrical current**).
• The current gets conducted into the tooth's root, usually by the filling or crown.
• The current sets off a nerve

An Arrhenius acid is a substance that dissociates in water to form hydrogen ions or protons. In other words, it increases the number of H⁺ ions in the water. In contrast, an Arrhenius base dissociates in water to form hydroxide ions, OH^-.

A Bronsted-Lowry acid is a solution that donates protons and is known as a proton donor. The Bronsted-Lowry base, on the other hand, is a solution that accepts protons and is known as a proton acceptor. Going back to a Bronsted-Lowry acid, in general, it must contain a hydrogen ion that it can give up.

Scientific Method

Ask a question.

Research.

Make a hypothesis.

Experiment and test your hypothesis.

Analyze your test results.

Present a conclusion.

Chemistry

Chemistry is the branch of science that studies the properties of matter and how matter interacts with energy.

Organic Chemistry

The branch of chemistry concerned with the study of compounds that contain the element carbon.

Inorganic Chemistry

The branch of chemistry concerned with the study of materials that contain any combination of chemical elements.

Element

A substance that cannot be broken into two or more simpler substances by any physical or chemical method and made of the same kind of atoms.

Compound

A molecule of a pure substance that contains two or more elements combined.

Heterogeneous Mixture

A... Continue reading "Scientific Method and Chemistry: An Introduction to Matter and Atoms" »

Mineral Definition and Fundamental Properties

Minerals are defined as: naturally occurring, inorganic, solids with a definite chemical composition, a regular crystalline structure, and specific and consistent physical properties. The fundamental aspects of this definition are a mineral's chemical composition, crystalline structure, and physical properties.

Different chemical compositions result in different minerals. A good example is the mineral plagioclase. Plagioclase is a member of the feldspar group, but there is more than one type. For instance, albite and anorthite are two examples. Albite has a chemical composition of NaAlSi₃O₈, while anorthite's chemical composition is CaAl₂Si₂O₈. Though very similar, their distinct compositions define... Continue reading "Mineral Identification: Properties and Structure" »

Water Quality Definitions

Alkalinity

Alkalinity: A measure of the water’s capability to absorb hydrogen ions without significant pH change (buffering capacity).

Problem 7-4: Settling Tank Design for Stillwater Water Plant Expansion

Design the settling tank(s) for the City of Stillwater’s water treatment plant expansion using the design overflow rate found in Example 7-3. The maximum day design flow is 0.5 m³/s. Assume a water temperature of 10° C.

Design Calculation Steps (Set 1)

1. Find the Surface Area

   Calculation: (0.5 m³/s) × (86,400 s/d) = 43,200 m³/d

2. Select the Number of Tanks

   

   = 221.66 or 222 m²/tank

3. Select a Trial Width for Calculation

   The maximum width for the chain-and-flight sludge collector is 6 m increments. Assume a width of 4 m.

4. Check

Q#9.2: Explain factors affecting rate of reaction.

Ans.The following factors strongly influence the rate of a reaction

1.Nature Of Reactants. The rate of reaction between polar or ionic

molecule is very fast. While the rearrangement reactions are slower than ionic reactions. Similarly oxidation reduction reactions are also slower than ionic. Some metals like sodium reacts vigorously with oxygen at room temp while magnesium needs flame to react with oxygen.

2.Effect Of Concentration Of Reactants.

By increasing the amount of reactants, the rate of reaction also increases. Consider a reaction which is composed of a gaseous mixture or concentrated solution, contains many active particles per unit volume. Therefore the rate of such reactions is faster... Continue reading "Key Factors Influencing Chemical Reaction Rates" »