Concentration Changes & Acid-Base Concepts
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Concentration Changes During Assessment
During an assessment, there must be an abrupt change in some property of the reaction mixture at the equivalence point. The property that changes depends on the volumetric reaction:
- Acid-base: An acid is titrated with a base, or vice versa. The abrupt change is due to a slight excess of one reactant, producing a sudden change in pH.
- Redox: An oxidant is titrated with a reducing agent, or vice versa. The abrupt change is due to a slight excess of one reactant, leading to a sudden change in the cell potential formed by two electrodes.
- Precipitation: An ionic substance is titrated with a precipitating reagent. The abrupt change is due to an excess of the precipitating reagent, which causes a sharp decrease in