Notes, summaries, assignments, exams, and problems for Chemistry

Atomic Structure

Elements are a type of atom. Atoms are made up of protons, neutrons, and electrons. The nucleus is the center of an atom.

• Proton: +1 charge
• Electron: -1 charge
• Neutron: 0 charge (neutral)

Rutherford (1911) conducted the gold foil experiment.

Different elements have different numbers of protons in the nucleus.

• Atomic number (Z): Number of protons
• Mass number (A): Number of protons + Number of neutrons

Z

Chemical Symbol

A

Neutron number = Mass number - Atomic number

The number of neutrons can change (protons stay the same) in a given atom, making them isotopes.

Atomic mass is the total mass of elements and all its isotopes. U represents atomic mass units.

A radioactive isotope consists of nuclides whose nuclei undergo spontaneous decay.

Three

Physical States of Matter

Physical States: Solid (Stones, salt, copper) / Liquid (Water, alcohol, gasoline) / Gaseous (Nitrogen, oxygen, hydrogen)

Do they have a fixed shape? Yes/No/No. Do they have a fixed volume? Yes/Yes/No. Are they easily compressible? No/No/Yes. Do they expand? No/No/Yes.

Kinetic Theory of Matter

Kinetic Matter is formed by very small particles (atoms) that are invisible even when using microscopes. The particles are in continuous movement. The higher the temperature, the faster they move. There are forces of attraction between the particles that make them group together. The farther the distance between the particles, the stronger these forces become.

States of Movement of the Particles:

• Speed of movement: Low, medium, high.

Foundational Concepts of Atomic Structure

Discovery of Subatomic Particles

• Electron: Discovered by J. J. Thomson (1897). Relative mass: 1/1837. Mass: 9.1 x 10⁻³¹ kg. Charge: -1.
• Proton: Discovered by Ernest Rutherford (1920). Relative mass: 1 atomic mass unit (u). Mass: 1.7 x 10⁻²⁷ kg. Charge: +1.
• Neutron: Discovered by James Chadwick (1932). Relative mass: 1 atomic mass unit (u). Mass: 1.7 x 10⁻²⁷ kg. Charge: 0.

Rutherford's Planetary Model (1911)

Ernest Rutherford proposed the Planetary Model, which is accepted today as the basic structure of the atom.

The atom consists of a very small central region, the nucleus, containing protons and neutrons, surrounded by orbiting electrons. The number of electrons equals the number of protons... Continue reading "Fundamentals of Atomic Structure and Periodic Trends" »

What is Surface Engineering?

Definition: It is the sub-discipline of material science which deals with the surface of solid matter.

Objectives: Involves altering the properties of the surface phase to reduce degradation over time, making it robust to the environment.

Applications: Automotive, aerospace, missile, power, electronic, biomedical, textile, petroleum, chemical, steel, power. Used in almost all types of materials.

Describe SEM and TEM

SEM: Scanning Electron Microscopy images the sample surface by scanning it with a high-energy beam of electrons. Advantages include 3D imaging and greater depth of focus. Disadvantages include low resolution and expensive equipment. Applications include gunshot residue analysis and firearms identification.... Continue reading "Surface Engineering and Microscopy Techniques in Material Science" »

Stoichiometry and Fixed Ratios

Fixed Ratios in Building and Manufacturing

Describe an experience you’ve had making or building something where the amount of each ingredient or building block came in fixed ratios.

Building a model airplane is an example. For each model, there must be two wings and three wheels. In order for the model to look correct or work properly, there must be a certain, unvarying number of wings and wheels.

Direct Arithmetic Units in Chemical Problems

A chemical problem may be presented to you in units of moles, mass, or volume. Which one of these can be directly used in your arithmetic no matter what the conditions are?

Moles can be directly used. The number of molecules or moles is the basic unit used in solving chemical... Continue reading "Chemical Calculations and Gas Law Principles: Stoichiometry and Kinetic Theory" »

Stoichiometry, Yields and Reaction Types

Solution

Solution — This is obtained when one chemical becomes completely dissolved in another.

Theoretical Yield

Theoretical yield — If a chemist calculates the maximum amount of product that could be obtained in a chemical reaction, he or she is calculating the theoretical yield.

Stoichiometry

Stoichiometry — Terms used to designate the calculations of quantities of substances involved in chemical reactions.

Percent Yield

Percent yield — This is obtained by dividing the actual yield by the theoretical yield and multiplying by 100%.

Limiting Reactant

Limiting reactant — The reactant that is fully consumed during the reaction.

Practice Questions

1.1 — In the equation 6 CO₂ + 6 H₂O ... the mole ratio... Continue reading "Stoichiometry, Reaction Types, and Yield Calculations" »

Kinetic Theory of Matter

• Matter is made up of particles.
• These particles are constantly moving because they have kinetic energy.
• There are spaces between the particles.
• There are attractive forces between particles, and these become stronger as the particles move closer.
• All particles have energy. The temperature of a substance is a measure of the average kinetic energy of the particles.
• A change in phase may occur when the energy of the particles is changed.

Boyle's Law

The pressure of a fixed quantity of gas is inversely proportional to the volume it occupies, as long as the temperature remains constant. P₁ × V₁ = P₂ × V₂

Gay-Lussac's and Charles's Law

The volume of an enclosed sample of gas is directly proportional to its absolute temperature, provided... Continue reading "Matter: Kinetic Theory, Properties, and Classifications" »

Scientific models used to explain why and how atoms form molecules:

• Lewis dot structure
• Valence bond theory

Valence bond theory describes a covalent bond as the overlap of half-filled atomic orbitals (each containing a single electron) that yield a pair of electrons shared between the two bonded atoms. According to valence bond theory, a covalent bond results when two conditions are met: (1) an orbital on one atom overlaps an orbital on a second atom and (2) the single electrons in each orbital combine to form an electron pair.

• Molecular orbital theory

model that describes the behavior of electrons delocalized throughout a molecule in terms of the combination of atomic wave functions. It describes the distribution of electrons in molecules in much... Continue reading "Atomic Models, Periodic Trends, and Chemical Bonding" »

IONIC: thet are solids at room temperatures and have medium to high meltin and boiling points. Ionic bond is strong because it is electrostatic. They are very hard. It is not eassy to scratch an ionic compound. They are fragile. Hitting them forces ions with the same signs together, and they repel and break the crystal. Most disolve well in water, water molecules may surround the ions,weakening their bonds and separating them from the crystal lattice. This is called solvation. They do not conduct electricity well in solid state but hey do in solution or liquid state. SODIUM CHLORIDE

Mixing and Measuring

Agitator

An agitator is a machine used for mixing liquids, typically with an electromagnet.

Beaker

A beaker is a cylindrical container made of glass that is very commonly used in the laboratory, mainly to prepare or heat substances.

Burette

A burette is used for decantation and for transferring and dispensing liquids or fluids.

Graduated Cylinder

A graduated cylinder is used to measure volumes of liquids.

Micropipettes

Micropipettes are used to measure and extract very small amounts of liquids from a solution.

Pipette

A pipette is used to accurately measure volumes of liquids.

Volumetric Flask

A volumetric flask is used to prepare solutions and to know the volume.

Heating and Support

Bunsen Burner

A Bunsen burner is used to heat chemical... Continue reading "Essential Lab Equipment: Uses and Functions" »